Antioxidant supps sure don't have much research backing up their health effects. And I've seen research indicating a shorter life for those who take the supps. No such research exists for fruits and veggies that are naturally high in anti oxidants, though. It's kind of weird. since a lot of foods that are good for you are thought to be so because or partly because of their anti oxidants, but when you supplement with anti oxidants, you don't really see any health benefits.
that's just one, though. If you do a google scholar search or pubmed you should be able to find quite a bit.
It makes you wonder if the antioxidants in natural foods for some reason help even though supplements don't. That would be kind of weird, since the supps have the same chemical structures as the real thing. Could it be what you take it in combination with? In fruits and veggies you have a buttload of different micronutrients, maybe the antioxidants help when you take it together with everything else in its natural package. Or maybe dietary antioxidants don't really help that much in the body, maybe the body makes just enough of them by itself and what really makes fruits and veggies so good for you is other stuff.